Create an Executable from Wordpress

I have this huge application that I want to create for an educational company to be running in a connection of schools. It contains more than 1000 revision papers and the same amount of answers. This is about 10000 pages which would be tedious to handle with a desktop programming language such as C or VB.net. After doing some research I found some free PHP to EXE converters. I later thought of designing the application using WordPres开发者_C百科s(add the questions and answers as posts) but I am not sure how possible this is (factors like Wordpress needs Apache). I would appreciate your suggestions on how to go about it if it is possible..

Php to EXE converter: http://www.bambalam.se/bamcompile/

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What about using WampServer to run PHP/MySql/Apache, but customizing the installer to install your customized wordpress site and launch the site